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KMID : 1024520020110040347
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Journal of the Environmental Sciences
2002 Volume.11 No. 4 p.347 ~ p.353
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The characteristics of chloramine formation and decay with pH variation
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Jo Kwan-Hyung
Kim Pyung-Chong
Woo Dal-Sik
Cho Young-Tai
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Abstract
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This study was conducted to investigate the characteristics of chloramination as a secondary disinfection in a drinking water distribution system. At the range from pH 6 to pH 8, monochloramine was predominant with a trace of dichloramine, and the free chlorine was detected after breakpoint. At , the breakpoints of pH 6, 7 and 8 appeared when the weight ratios of chlorine to ammonia nitrogen were 11:1, 9:1 and 10:1 respectively, and the peak points on the breakpoint curves at pH 6, 7 and 8 were in the Cl / NH-N ratio of 9:1, 6:1 and 5:1 respectively. As pH increased from 6 to 8, maximum point of monochloramine on the breakpoint curve was moved from 7:1 to 5:1 in the weight ratio of chlorine to ammonia nitrogen. The maximum concentration of monochloramine was formed at the pH values of 7~8 and in the Cl / NH-N ratio below 5:1. As the Cl/NH-N ratio increased and the pH lowered, chloramines decay proceeded at an increased rate, and residual chloramines lasted longer than the residual free chlorine. The monochloramine and the dichloramine were formed at pH 6, and then the dichloramine continued increasing with contact time.
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KEYWORD
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residual free chlorine, chloramination, monochloramine
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